§16§§This book constitutes the refereed proceedings of the 16th IFIP WG 5.5/SOCOLNET Advanced Doctoral Conference on Computing, Electrical and Industrial Systems on Technological Innovation for AI-Powered Cyber-Physical Systems, DoCEIS 2025, held in Lisbon, Portugal, during July 2 4, 2025.§§The 29 full papers presented were carefully reviewed and selected from 60 submissions. They were focused on topical sections as follows: AI in Business Applications; AI in Industry 4.0; Smart Systems in Sustainable Development; AI-Powered Healthcare; AI in Systems, Decision 〓 Intelligent Sensing 〓 Smart Power Systems; Electronic Systems.§ §04§§.- AI in Business Applications.§.- A Collaborative Approach to Last-Mile Logistics.§.- Processes Classification Tool Development Based on BERT for Logistics Laboratory.§.- An Access Control Method Against Unauthorized and Noncompliant Behaviors Leveraging Large Language Models.§.- A Pattern-Based Approach to Data Privacy in Business Processes.§.- AI in Industry 4.0.§.- Large Language Models to Support Altruistic Collaborative Healing in Smart Manufacturing.§.- Data Pre-processing of Hard Disk Drive Data for failure prediction in the context of Industry 4.0.§.- Forecasting Power Demand in Complex Buildings Using Machine Learning: A Shopping Center Case Study.§.- Smart Systems in Sustainable Development.§.- Ensemble Deep Learning Model for AI-Powered Cyber-Physical Systems in Precision Agriculture.§.- An Integrated Framework for the Development of a Multi-Sensor Node to Support Wildfire Management.§.- Detection and Characterization of Plume-Do §04§minated Wildfires.§.- AI-Powered Healthcare.§.- Device Prototype for Kinematic and Electromyographic Analysis of the Upper Limb.§.- Explainable Normative Modeling: Subcortical Changes in Frontotemporal Dementia Subtypes.§.- User-Centered and Technical Requirements for Myoelectric Pediatric Arm Prosthesis Design: A Preliminary Study.§.- Embedding Predecessor Information in Optimization of Genetic Algorithm (GA) based Blind Image Restor§