Metal Vapour Synthesis (MVS) can be defined as; "The use in synthesis of high temper ature gaseous species such as metal atoms by their reactions with themselves or other materials in a condensed phase. " This short book, covering the literature up to the middle of 1979, describes MVS in organic chemistry; i. e. the reactions of metal atoms with various, predominantly organic, substrates in the synthesis and reactivity studies of organic and organometallic compounds. In order to effectively describe all the underlying principles and to present a coesive picture of pertinent metal atom processes in condensed organic phases, some inorganic substrates such as rare gases, dinitrogen, dioxygen, dihalo gens, and inorganic halides have been included. For similar reasons, we have used, where relevent, information provided by the closely related technique of Matrix Isolation Spec troscopy (MIS). After an introductory chapter which gives the basis principles and includes a brief critique of the technique, the book is divided into three further chapters dealing respec tively with (a) experimental techniques, (b) behaviour of metal atoms in matrices, and (c) results of prep~rative experiments. While not being encyclopaedic the book describes or refers to all noteworthy areas if not in the deliberately short text in the many tables and figures. 1 The Basic Principles.- 1.1 Introduction.- 1.2 The Method.- 1.3 The Scope of the Technique.- 2 Practical Aspects of Metal Vapour Synthesis.- 2.1 General Considerations.- 2.2 Pumping Systems.- 2.3 Vacuum Vessels.- 2.4 Reactant Inlet Systems.- 2.5 Vacuum Sealed Inlets for Electrical Supply.- 2.6 Pressure Measurement.- 2.7 Vaporisation Sources.- 2.8 Vaporisation Sources for Matrix Isolation Spectroscopy.- 2.9 Leak Detection.- 2.10 General Experimental Procedures.- 3 Properties of Metal Atoms and Interactions with Atoms and Molecules in Condensed Phases.- 3.1 Introduction.- 3.2 Metal Atoms in Matrices.- 3.3 Metal-Metal Interactions: Aggregation.- 4 The Reactions of Metal Atoms.- 4.1 Types of Reaction.- 4.2 Carbon Monoxide.- 4.3 Carbon Monosulfide.- 4.4 Carbon Dioxide, Carbon Oxysulfide and Carbon Disulfide.- 4.5 Dinitrogen.- 4.6 Nitrogen Oxides.- 4.7 Phosphines and Phosphites.- 4.8 Isocyanides.- 4.9 Alkynes.- 4.10 Alkenes.- 4.11 Allyl.- 4.12 Alkadienes.- 4.14 Styrene.- 4.15 Alkatetraenes.- 4.16 Heterocycles.- 4.17 Boranes and Carboranes.- 4.18 Organic Halides.- 4.19 Grignard Reagents.- 4.20 Inorganic Halides.- 4.21 Acids.- 4.22 Dioxygen.- 4.23 Dihalogens.- 4.24 Oxygen-Containing Organic Compounds.- 4.25 Sulfur-Containing Organic Compounds.- References.- Latest Developments in Metal Vapour Synthesis.
